指南卡 139
译本:机器初稿
物质——遇水反应(释放易燃和有毒气体)
Substances - Water-Reactive (Emitting Flammable and Toxic Gases)
中国境内请拨:火警 119 · 急救 120 · 报警 110;化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090(24 小时)。英文原文沿用 ERG 原版(美国为 911)。
潜在危害(火灾与爆炸)
接触水产生易燃和有毒气体。
Produce flammable and toxic gases on contact with water.接触水或潮湿空气可能点燃。
May ignite on contact with water or moist air.某些物质接触水时剧烈反应或发生爆炸性反应。
Some react vigorously or explosively on contact with water.可能被热、火花或火焰点燃。
May be ignited by heat, sparks or flames.火灾扑灭后可能复燃。
May re-ignite after fire is extinguished.某些以高易燃液体作溶剂运输。
Some are transported in highly flammable liquids.容器受热可能爆炸。
Containers may explode when heated.径流可能造成火灾或爆炸危险。
Runoff may create fire or explosion hazard.健康危害
剧毒:接触水产生有毒气体,吸入可致命。
Highly toxic: contact with water produces toxic gas, may be fatal if inhaled.吸入或接触蒸气、物质或分解产物可能造成重伤或死亡。
Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death.接触水可能生成腐蚀性溶液。
May produce corrosive solutions on contact with water.火灾会产生刺激性、腐蚀性和(或)毒性气体。
Fire will produce irritating, corrosive and/or toxic gases.灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.公众安全
拨打 119(火警)/120(急救)/110(报警)。然后拨打运输单据上的应急响应电话号码;如无运输单据或无人接听,请拨国家化学事故应急咨询专线 0532-83889090(24 小时),或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.无关人员远离。
Keep unauthorized personnel away.位于上风向、地势较高处和(或)上游。
Stay upwind, uphill and/or upstream.进入密闭空间前先通风,但仅在受过训练并配备装备时进行。
Ventilate closed spaces before entering, but only if properly trained and equipped.立即预防措施
Immediate precautionary measure向四周隔离泄漏区,液体至少 50 米(150 英尺),固体至少 25 米(75 英尺)。
Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.泄漏
Spill高亮标注的物质:见表 1——初始隔离和防护距离。
For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.未高亮标注的物质:必要时在下风向加大立即预防措施的距离。
For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.火灾
Fire如罐车、铁路罐车或公路罐车涉及火灾,向四周隔离 800 米(1/2 英里);同时考虑向四周 800 米(1/2 英里)实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.消防措施
切勿使用水或泡沫。(氯硅烷可用泡沫,见下文)
DO NOT USE WATER OR FOAM. (FOAM MAY BE USED FOR CHLOROSILANES, SEE BELOW)小面积火灾
Small Fire干粉、纯碱、石灰或沙子。
Dry chemical, soda ash, lime or sand.大面积火灾
Large Fire干沙、干粉、纯碱或石灰,或者撤离现场让其燃烧。
DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.对氯硅烷,切勿用水;使用抗溶泡沫;扑救氯硅烷火灾(大小火)时切勿使用干粉、纯碱或石灰,因其可能释放大量氢气并导致爆炸。
FOR CHLOROSILANES, DO NOT USE WATER; use alcohol-resistant foam; DO NOT USE dry chemicals, soda ash or lime on chlorosilane fires (large or small) as they may release large quantities of hydrogen gas that may explode.在安全可行的情况下,将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.罐车火灾(罐车、铁路罐车或公路罐车)
Fire Involving Tanks, Rail Tank Cars or Highway Tanks从最远距离灭火,或使用无人操作的大口径水枪或遥控水炮。
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.用大量水冷却容器,直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.切勿让水进入容器内部。
Do not get water inside containers.如泄压安全装置发出声响增大或罐体变色,立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.防护服
佩戴正压自给式呼吸器(SCBA)。
Wear positive pressure self-contained breathing apparatus (SCBA).在无火灾风险时,穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.消防员结构防护服可提供热防护,但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.泄漏处置
消除周边区域的一切点火源(禁止吸烟、明火、火花或火焰)。
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.在无风险的情况下堵漏。
Stop leak if you can do it without risk.切勿让水接触泄漏物或进入容器内部。
DO NOT GET WATER on spilled substance or inside containers.用喷雾水降低蒸气浓度或改变蒸气云漂移方向。避免径流接触泄漏物。
Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.对氯硅烷,使用抗溶泡沫降低蒸气。
FOR CHLOROSILANES, use alcohol-resistant foam to reduce vapors.少量泄漏
Small Spill用干土、干沙或其他不燃材料覆盖,再盖上塑料布,以减少扩散或与雨水接触。
Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain.筑堤围堵待后续处置;除非另有指示,否则不要用水。
Dike for later disposal; do not apply water unless directed to do so.粉末泄漏
Powder Spill用塑料布或防水布覆盖粉末泄漏物,以减少扩散并保持粉末干燥。
Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.除专家监督外,切勿清理或处置。
DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.急救
特殊急救:
Specific First Aid:如接触该物质,立即从皮肤上擦除;用流动清水冲洗皮肤或眼睛至少 20 分钟。
In case of contact with substance, wipe from skin immediately; flush skin or eyes with running water for at least 20 minutes.在加拿大,本产品可能要求制定应急响应援助计划(ERAP)。请查阅运输单据和(或)「ERAP」章节。
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.适用物质(29 个物质)
- 乙基二氯硅烷 UN 1183
- 甲基二氯硅烷 UN 1242
- 三氯硅烷 UN 1295
- 七硫化四磷,不含黄磷和白磷 UN 1339
- 五硫化二磷,不含黄磷和白磷 UN 1340
- 三硫化四磷,不含黄磷和白磷 UN 1341
- 三硫化二磷,不含黄磷和白磷 UN 1343
- 磷化钙 UN 1360
- 氨基碱金属 UN 1390
- 硅铝铁合金粉 UN 1395
- 磷化铝 UN 1397
- 硅铁,含硅30%-90% UN 1408
- 磷化铝镁 UN 1419
- 磷化钠 UN 1432
- 磷化锡 UN 1433
- 磷化锌 UN 1714
- 二磷化三镁 UN 2011
- 磷化钾 UN 2012
- 磷化锶 UN 2013
- 氮化锂 UN 2806
- 锂硅铁 UN 2830
- 三氟化硼合二甲醚 UN 2965
- 氯硅烷,遇水反应,易燃,腐蚀性,未另作规定的 UN 2988
- 毒性液体,遇水反应,未另作规定的 UN 3123
- 毒性固体,遇水反应,未另作规定的 UN 3125
- 遇水反应液体,毒性,未另作规定的 UN 3130
- 遇水反应固体,毒性,未另作规定的 UN 3134
- 吸入毒性液体,遇水反应,未另作规定的,LC50低于或等于200毫升/立方米,且饱和蒸气浓度大于或等于500LC50 UN 3385
- 吸入毒性液体,遇水反应,未另作规定的,LC50低于或等于1000毫升/立方米,且饱和蒸气浓度大于或等于10LC50 UN 3386