UN 1021 指南卡 126

1-氯-1,2,2,2-四氟乙烷

1-Chloro-1,2,2,2-tetrafluoroethane

危险性类别
2.2
包装类别
—
指南卡
126 · 气体——压缩或液化(含制冷气体)

TDG 运输品名(联合国《规章范本》)

正式运输品名危险性类别副危险包装类别
1-氯-1,2,2,2-四氟乙烷2.2 ——

《危险化学品目录》关联

  • 氯四氟乙烷 CAS 63938-10-3 PubChem 桥接 加压气体;特异性靶器官毒性-一次接触,类别3(麻醉效应);危害臭氧层,类别1
全部可检索名称(3)
  • 1-氯-1,2,2,2-四氟乙烷official · zh
  • 1-Chloro-1,2,2,2-tetrafluoroethaneen · en
  • 1-氯-1,2,2,2-四氟乙烷(制冷气体R 124)jbl · zh

潜在危害(火灾与爆炸)

某些可能燃烧,但均不易点燃。
Some may burn but none ignite readily.
容器受热可能爆炸。
Containers may explode when heated.
破裂的气瓶可能飞出。
Ruptured cylinders may rocket.
注意:气雾剂(UN1950)可能含易燃推进剂。
CAUTION: Aerosols (UN1950) may contain a flammable propellant.

健康危害

蒸气可能毫无预警地引起头晕或窒息,在密闭或受限区域尤为如此。
Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.
液化气蒸气初期比空气重,沿地面扩散。
Vapors from liquefied gas are initially heavier than air and spread along ground.
接触气体或液化气体可能造成灼伤、重伤和(或)冻伤。
Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
火灾可能产生刺激性、腐蚀性和(或)毒性气体。
Fire may produce irritating, corrosive and/or toxic gases.

公众安全

拨打 119(火警)/120(急救)/110(报警)。然后拨打运输单据上的应急响应电话号码;如无运输单据或无人接听,请拨国家化学事故应急咨询专线 0532-83889090(24 小时),或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
无关人员远离。
Keep unauthorized personnel away.
位于上风向、地势较高处和(或)上游。
Stay upwind, uphill and/or upstream.
许多气体比空气重,会沿地面扩散并积聚在低洼或受限区域(下水道、地下室、罐体等)。
Many gases are heavier than air and will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
进入密闭空间前先通风,但仅在受过训练并配备装备时进行。
Ventilate closed spaces before entering, but only if properly trained and equipped.
立即预防措施
Immediate precautionary measure
向四周隔离泄漏区至少 100 米(330 英尺)。
Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
大量泄漏
Large Spill
考虑在下风向至少 500 米(1/3 英里)范围内实施初始疏散。
Consider initial downwind evacuation for at least 500 meters (1/3 mile).
火灾
Fire
如罐车、铁路罐车或公路罐车涉及火灾,向四周隔离 800 米(1/2 英里);同时考虑向四周 800 米(1/2 英里)实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

消防措施

使用适合周围火情的灭火剂。
Use extinguishing agent suitable for type of surrounding fire.
小面积火灾
Small Fire
干粉或二氧化碳。
Dry chemical or CO2.
大面积火灾
Large Fire
喷雾水、雾状水或普通泡沫。
Water spray, fog or regular foam.
在安全可行的情况下,将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.
破损气瓶只能由专业人员处理。
Damaged cylinders should be handled only by specialists.
罐车火灾
Fire Involving Tanks
从最远距离灭火,或使用无人操作的大口径水枪或遥控水炮。
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
用大量水冷却容器,直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.
切勿将水直接射向泄漏源或安全装置;可能发生结冰。
Do not direct water at source of leak or safety devices; icing may occur.
如泄压安全装置发出声响增大或罐体变色,立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.
其中某些物质泄漏后可能蒸发,留下易燃残留物。
Some of these materials, if spilled, may evaporate leaving a flammable residue.

防护服

佩戴正压自给式呼吸器(SCBA)。
Wear positive pressure self-contained breathing apparatus (SCBA).
在无火灾风险时,穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
消防员结构防护服可提供热防护,但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

泄漏处置

切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.
在无风险的情况下堵漏。
Stop leak if you can do it without risk.
切勿将水直接射向泄漏物或泄漏源。
Do not direct water at spill or source of leak.
用喷雾水降低蒸气浓度或改变蒸气云漂移方向。避免径流接触泄漏物。
Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.
如有可能,翻转泄漏容器,使气体逸出而非液体流出。
If possible, turn leaking containers so that gas escapes rather than liquid.
防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.
让该物质自然蒸发。
Allow substance to evaporate.
对该区域通风。
Ventilate the area.

急救

通用急救措施(各卡一致(18)
一般急救:
General First Aid:
拨打 120(急救)或呼叫急救医疗服务。
Call 911 or emergency medical service.
确保医务人员了解所涉及的物质,采取防护措施保护自身并避免沾染。
Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
在安全可行的情况下,将伤员移至新鲜空气处。
Move victim to fresh air if it can be done safely.
呼吸困难时给予吸氧。
Administer oxygen if breathing is difficult.
如伤员无呼吸:
If victim is not breathing:
切勿进行口对口人工呼吸;伤员可能已吞入或吸入该物质。
DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.
如具备条件且触及脉搏,清洗面部和口腔,然后使用合格的呼吸急救装置(球囊面罩、带单向阀的口袋面罩或其他装置)进行人工呼吸。
If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
如未触及脉搏或无呼吸急救装置,实施持续胸外按压。每两分钟检查一次脉搏,或观察有无自主呼吸的迹象。
If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
脱去并隔离受污染的衣物和鞋子。
Remove and isolate contaminated clothing and shoes.
少量皮肤接触时,避免将物质扩散到未受污染的皮肤上。
For minor skin contact, avoid spreading material on unaffected skin.
如接触该物质,立即用流动清水冲洗皮肤或眼睛至少 20 分钟。
In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
严重烧伤须立即就医。
For severe burns, immediate medical attention is required.
接触该物质(吸入、吞入或皮肤接触)后的症状可能出现延迟。
Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
保持伤员安静并保暖。
Keep victim calm and warm.
对伤员持续观察。
Keep victim under observation.
如需进一步救助,请联系当地中毒控制中心。
For further assistance, contact your local Poison Control Center.
注:基础生命支持(BLS)和高级生命支持(ALS)应由受过训练的专业人员实施。
Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.

本物质专项急救

特殊急救:
Specific First Aid:
如接触液化气体,结霜部位只能由医务人员尝试解冻。
In case of contact with liquefied gas, only medical personnel should attempt thawing frosted parts.
中国境内请拨:火警 119 · 急救 120 · 报警 110;化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090(24 小时)。英文原文沿用 ERG 原版(美国为 911)。

权威数据源 · 更多资料

以上为第三方/官方站点,在本站新窗口打开;ICSC 未收录的化学品可能显示「未查到」,属正常结果。

以上内容来自 ERG 2024(美国政府作品)与机器翻译初稿,仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本;翻译未经专业复核的部分以英文原文为准。