UN 1456 指南卡 140

高锰酸钙

Calcium permanganate

危险性类别: 5.1
包装类别: II
指南卡: 140 · 氧化剂

TDG 运输品名（联合国《规章范本》）

正式运输品名	危险性类别	副危险	包装类别
高锰酸钙	5.1	—	II

《危险化学品目录》关联

高锰酸钙 CAS 10118-76-0 名称一致氧化性固体,类别2

全部可检索名称（2）

高锰酸钙official · zh
Calcium permanganateen · en

潜在危害（火灾与爆炸）

注意：硝酸铵类产品涉及火灾、被烃类（燃料）、有机物或其他污染物污染，或处于热熔融且密闭状态时，可能爆炸。按爆炸品处置（指南 112）。

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).

这些物质涉及火灾时会加速燃烧。

These substances will accelerate burning when involved in a fire.

某些受热或涉及火灾时可能发生爆炸性分解。

Some may decompose explosively when heated or involved in a fire.

受热或混入杂质可能爆炸。

May explode from heat or contamination.

某些会与烃类（燃料）发生爆炸性反应。

Some will react explosively with hydrocarbons (fuels).

可能点燃可燃物（木材、纸张、油类、衣物等）。

May ignite combustibles (wood, paper, oil, clothing, etc.).

容器受热可能爆炸。

Containers may explode when heated.

径流可能造成火灾或爆炸危险。

Runoff may create fire or explosion hazard.

健康危害

吸入、吞入或接触（皮肤、眼睛）蒸气或该物质可能造成重伤、灼伤或死亡。

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

火灾可能产生刺激性、腐蚀性和（或）毒性气体。

Fire may produce irritating, corrosive and/or toxic gases.

灭火用水或稀释水的径流可能造成环境污染。

Runoff from fire control or dilution water may cause environmental contamination.

公众安全

拨打 119（火警）/120（急救）/110（报警）。然后拨打运输单据上的应急响应电话号码；如无运输单据或无人接听，请拨国家化学事故应急咨询专线 0532-83889090（24 小时），或查阅封底内页所列的相应电话号码。

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

无关人员远离。

Keep unauthorized personnel away.

位于上风向、地势较高处和（或）上游。

Stay upwind, uphill and/or upstream.

进入密闭空间前先通风，但仅在受过训练并配备装备时进行。

Ventilate closed spaces before entering, but only if properly trained and equipped.

立即预防措施

Immediate precautionary measure

向四周隔离泄漏区，液体至少 50 米（150 英尺），固体至少 25 米（75 英尺）。

Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

大量泄漏

Large Spill

考虑在下风向至少 100 米（330 英尺）范围内实施初始疏散。

Consider initial downwind evacuation for at least 100 meters (330 feet).

火灾

Fire

如罐车、铁路罐车或公路罐车涉及火灾，向四周隔离 800 米（1/2 英里）；同时考虑向四周 800 米（1/2 英里）实施初始疏散。

If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

如硝酸铵类产品位于罐体、铁路罐车或货车中且涉及火灾，向四周隔离 1600 米（1 英里）；同时向四周 1600 米（1 英里）实施疏散，包括应急响应人员。

If ammonium nitrate products are in a tank, rail car or truck and involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions.

消防措施

小面积火灾

Small Fire

用水。切勿使用干粉或泡沫。二氧化碳或哈龙® 可能仅能有限控制。

Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.

大面积火灾

Large Fire

从远处向火场大量注水。

Flood fire area with water from a distance.

货物已受热时，切勿移动货物或车辆。

Do not move cargo or vehicle if cargo has been exposed to heat.

在安全可行的情况下，将未受损的容器移离火场周边区域。

If it can be done safely, move undamaged containers away from the area around the fire.

罐车火灾（罐车、铁路罐车或公路罐车）

Fire Involving Tanks, Rail Tank Cars or Highway Tanks

对硝酸铵类产品：切勿扑救货物火灾。撤离、疏散并向四周至少 1600 米（1 英里）隔离。按爆炸品处置（指南 112）。24 小时内或未获专家意见前不得进入该区域。

For ammonium nitrate products: Do not fight cargo fire. Withdraw, evacuate and isolate area for at least 1600 meters (1 mile). Treat as an explosive (GUIDE 112). Do not enter area for 24 hours or until expert advice has been provided.

从最远距离灭火，或使用无人操作的大口径水枪或遥控水炮。

Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.

用大量水冷却容器，直至火灾扑灭后很长时间。

Cool containers with flooding quantities of water until well after fire is out.

始终远离直接接触火焰的罐体。

ALWAYS stay away from tanks in direct contact with flames.

大面积火灾时，使用无人操作的大口径水枪或遥控水炮；如无法做到，撤离现场并让其燃烧。

For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

防护服

佩戴正压自给式呼吸器（SCBA）。

Wear positive pressure self-contained breathing apparatus (SCBA).

在无火灾风险时，穿着制造商专门推荐的化学防护服。

Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.

消防员结构防护服可提供热防护，但化学防护能力有限。

Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

泄漏处置

使可燃物（木材、纸张、油类等）远离泄漏物。

Keep combustibles (wood, paper, oil, etc.) away from spilled material.

未穿着适当防护服时，切勿触碰破损容器或泄漏物。

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

在无风险的情况下堵漏。

Stop leak if you can do it without risk.

切勿让水进入容器内部。

Do not get water inside containers.

少量干泄漏

Small Dry Spill

用清洁的铲子将物质装入清洁干燥的容器，松松盖上；将容器移出泄漏区。

With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.

少量液体泄漏

Small Liquid Spill

使用蛭石或沙子等不燃材料吸附该产品，放入容器中待后续处置。

Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.

大量泄漏

Large Spill

在液体泄漏物前方较远处筑堤围堵，待后续处置。

Dike far ahead of liquid spill for later disposal.

急救

通用急救措施（各卡一致（18）

一般急救：

General First Aid:

拨打 120（急救）或呼叫急救医疗服务。

Call 911 or emergency medical service.

确保医务人员了解所涉及的物质，采取防护措施保护自身并避免沾染。

Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.

在安全可行的情况下，将伤员移至新鲜空气处。

Move victim to fresh air if it can be done safely.

呼吸困难时给予吸氧。

Administer oxygen if breathing is difficult.

如伤员无呼吸：

If victim is not breathing:

切勿进行口对口人工呼吸；伤员可能已吞入或吸入该物质。

DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.

如具备条件且触及脉搏，清洗面部和口腔，然后使用合格的呼吸急救装置（球囊面罩、带单向阀的口袋面罩或其他装置）进行人工呼吸。

If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).

如未触及脉搏或无呼吸急救装置，实施持续胸外按压。每两分钟检查一次脉搏，或观察有无自主呼吸的迹象。

If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.

脱去并隔离受污染的衣物和鞋子。

Remove and isolate contaminated clothing and shoes.

少量皮肤接触时，避免将物质扩散到未受污染的皮肤上。

For minor skin contact, avoid spreading material on unaffected skin.

如接触该物质，立即用流动清水冲洗皮肤或眼睛至少 20 分钟。

In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.

严重烧伤须立即就医。

For severe burns, immediate medical attention is required.

接触该物质（吸入、吞入或皮肤接触）后的症状可能出现延迟。

Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.

保持伤员安静并保暖。

Keep victim calm and warm.

对伤员持续观察。

Keep victim under observation.

如需进一步救助，请联系当地中毒控制中心。

For further assistance, contact your local Poison Control Center.

注：基础生命支持（BLS）和高级生命支持（ALS）应由受过训练的专业人员实施。

Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.

本物质专项急救

特殊急救：

Specific First Aid:

受污染的衣物干燥后可能有火灾风险。

Contaminated clothing may be a fire risk when dry.

在加拿大，本产品可能要求制定应急响应援助计划（ERAP）。请查阅运输单据和（或）「ERAP」章节。

In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.

中国境内请拨：火警 119 · 急救 120 · 报警 110；化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090（24 小时）。英文原文沿用 ERG 原版（美国为 911）。

理化性质

PubChem 实验值

来自关联条目高锰酸钙 CAS 10118-76-0 ——UN 条目常是类名，具体物质不同则数值可能不同，以 SDS 为准。

外观与性状: Calcium permanganate is a purple crystalline solid. It is used as a disinfectant and deodorizer, in water purification, and for many other uses.
颜色: Violet or dark-purple deliquescent crystals
密度: 2.4 g/cu cm
溶解性: Freely soluble in water

数据来自 PubChem（美国 NIH/NLM，CID 24959）实验值摘录，保留原值与单位未做换算。

以上为第三方/官方站点，在本站新窗口打开；ICSC 未收录的化学品可能显示「未查到」，属正常结果。

以上内容来自 ERG 2024（美国政府作品）与机器翻译初稿，仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本；翻译未经专业复核的部分以英文原文为准。