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UN 2006 指南卡 135

塑料，以硝化纤维素为基料，自热性，未另作规定的

Plastics, nitrocellulose-based, self-heating, n.o.s.

危险性类别
4.2
包装类别
III
指南卡
135 · 物质——自燃

TDG 运输品名（联合国《规章范本》）

正式运输品名危险性类别副危险包装类别
塑料，以硝化纤维素为基料，自热性，未另作规定的4.2 —III
全部可检索名称（2）
  • 塑料，以硝化纤维素为基料，自热性，未另作规定的official · zh
  • Plastics, nitrocellulose-based, self-heating, n.o.s.en · en

潜在危害（火灾与爆炸）

易燃或可燃物质。
Flammable/combustible material.
接触潮湿空气或水分可能点燃。
May ignite on contact with moist air or moisture.
可能迅速燃烧并呈喷燃效应。
May burn rapidly with flare-burning effect.
某些物质接触水时剧烈反应或发生爆炸性反应。
Some react vigorously or explosively on contact with water.
某些受热或涉及火灾时可能发生爆炸性分解。
Some may decompose explosively when heated or involved in a fire.
火灾扑灭后可能复燃。
May re-ignite after fire is extinguished.
径流可能造成火灾或爆炸危险。
Runoff may create fire or explosion hazard.
容器受热可能爆炸。
Containers may explode when heated.

健康危害

火灾会产生刺激性、腐蚀性和（或）毒性气体。
Fire will produce irritating, corrosive and/or toxic gases.
吸入分解产物可能造成重伤或死亡。
Inhalation of decomposition products may cause severe injury or death.
接触该物质可能造成皮肤和眼睛严重灼伤。
Contact with substance may cause severe burns to skin and eyes.
灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.
注意：戊硼烷（UN1380）剧毒，吸入、吞入或经皮肤吸收可致命。
CAUTION: Pentaborane (UN1380) is highly toxic and may be fatal if inhaled, ingested or absorbed through skin.

公众安全

拨打 119（火警）/120（急救）/110（报警）。然后拨打运输单据上的应急响应电话号码；如无运输单据或无人接听，请拨国家化学事故应急咨询专线 0532-83889090（24 小时），或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
位于上风向、地势较高处和（或）上游。
Stay upwind, uphill and/or upstream.
无关人员远离。
Keep unauthorized personnel away.
立即预防措施
Immediate precautionary measure
向四周隔离泄漏区，液体至少 50 米（150 英尺），固体至少 25 米（75 英尺）。
Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
泄漏
Spill
高亮标注的物质：见表 1——初始隔离和防护距离。
For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
未高亮标注的物质：必要时在下风向加大立即预防措施的距离。
For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.
火灾
Fire
如罐车、铁路罐车或公路罐车涉及火灾，向四周隔离 800 米（1/2 英里）；同时考虑向四周 800 米（1/2 英里）实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

消防措施

切勿将水、二氧化碳或泡沫直接施于物质本身。
DO NOT USE WATER, CO2 OR FOAM ON MATERIAL ITSELF.
其中某些物质可能与水剧烈反应。
Some of these materials may react violently with water.
注意：对黄原酸盐 UN3342 及连二亚硫酸盐（保险粉）UN1384、UN1923、UN1929，扑救小火和大火均须用大量水淹没以终止反应。对这些物质窒息法无效，其燃烧不需要空气。
CAUTION: For Xanthates, UN3342 and for Dithionite (Hydrosulfite/Hydrosulphite) UN1384, UN1923 and UN1929, USE FLOODING AMOUNTS OF WATER for SMALL AND LARGE fires to stop the reaction. Smothering will not work for these materials, they do not need air to burn.
小面积火灾
Small Fire
干粉、纯碱、石灰或干沙（UN1384、UN1923、UN1929 和 UN3342 除外）。
Dry chemical, soda ash, lime or DRY sand, EXCEPT for UN1384, UN1923, UN1929 and UN3342.
大面积火灾
Large Fire
干沙、干粉、纯碱或石灰（UN1384、UN1923、UN1929 和 UN3342 除外），或者撤离现场让其燃烧。
DRY sand, dry chemical, soda ash or lime EXCEPT for UN1384, UN1923, UN1929 and UN3342, or withdraw from area and let fire burn.
注意：UN3342 遇水淹没后会持续释放易燃的二硫化碳蒸气。
CAUTION: UN3342 when flooded with water will continue to evolve flammable Carbon disulfide/Carbon disulphide vapors.
在安全可行的情况下，将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.
罐车火灾（罐车、铁路罐车或公路罐车）
Fire Involving Tanks, Rail Tank Cars or Highway Tanks
从最远距离灭火，或使用无人操作的大口径水枪或遥控水炮。
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
切勿让水进入容器内部或接触该物质。
Do not get water inside containers or in contact with substance.
用大量水冷却容器，直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.
如泄压安全装置发出声响增大或罐体变色，立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.

防护服

佩戴正压自给式呼吸器（SCBA）。
Wear positive pressure self-contained breathing apparatus (SCBA).
在无火灾风险时，穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
消防员结构防护服可提供热防护，但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

泄漏处置

消除周边区域的一切点火源（禁止吸烟、明火、火花或火焰）。
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.
在无风险的情况下堵漏。
Stop leak if you can do it without risk.
少量泄漏
Small Spill
注意：黄原酸盐 UN3342 及连二亚硫酸盐（保险粉）UN1384、UN1923、UN1929 泄漏时，用 5 倍水溶解后收集，妥善处置。
CAUTION: For spills of Xanthates, UN3342 and for Dithionite (Hydrosulfite/Hydrosulphite), UN1384, UN1923 and UN1929, dissolve in 5 parts water and collect for proper disposal.
注意：UN3342 遇水淹没后会持续释放易燃的二硫化碳蒸气。
CAUTION: UN3342 when flooded with water will continue to evolve flammable Carbon disulfide/Carbon disulphide vapors.
用干土、干沙或其他不燃材料覆盖，再盖上塑料布，以减少扩散或与雨水接触。
Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain.
使用清洁、无火花的工具收集物质，放入带松盖的塑料容器中待后续处置。
Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal.
防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.

急救

通用急救措施（各卡一致（19）
一般急救：
General First Aid:
拨打 120（急救）或呼叫急救医疗服务。
Call 911 or emergency medical service.
确保医务人员了解所涉及的物质，采取防护措施保护自身并避免沾染。
Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
在安全可行的情况下，将伤员移至新鲜空气处。
Move victim to fresh air if it can be done safely.
呼吸困难时给予吸氧。
Administer oxygen if breathing is difficult.
如伤员无呼吸：
If victim is not breathing:
切勿进行口对口人工呼吸；伤员可能已吞入或吸入该物质。
DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.
如具备条件且触及脉搏，清洗面部和口腔，然后使用合格的呼吸急救装置（球囊面罩、带单向阀的口袋面罩或其他装置）进行人工呼吸。
If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
如未触及脉搏或无呼吸急救装置，实施持续胸外按压。每两分钟检查一次脉搏，或观察有无自主呼吸的迹象。
If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
脱去并隔离受污染的衣物和鞋子。
Remove and isolate contaminated clothing and shoes.
少量皮肤接触时，避免将物质扩散到未受污染的皮肤上。
For minor skin contact, avoid spreading material on unaffected skin.
如接触该物质，立即用流动清水冲洗皮肤或眼睛至少 20 分钟。
In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
严重烧伤须立即就医。
For severe burns, immediate medical attention is required.
接触该物质（吸入、吞入或皮肤接触）后的症状可能出现延迟。
Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
保持伤员安静并保暖。
Keep victim calm and warm.
对伤员持续观察。
Keep victim under observation.
如需进一步救助，请联系当地中毒控制中心。
For further assistance, contact your local Poison Control Center.
注：基础生命支持（BLS）和高级生命支持（ALS）应由受过训练的专业人员实施。
Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.
在加拿大，本产品可能要求制定应急响应援助计划（ERAP）。请查阅运输单据和（或）「ERAP」章节。
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.
中国境内请拨：火警 119 · 急救 120 · 报警 110；化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090（24 小时）。英文原文沿用 ERG 原版（美国为 911）。

权威数据源 · 更多资料

国际化学品安全卡（ICSC 中文版）ILO/WHO 编制的权威安全卡，收录约 1785 种常见危化品：危害、急救、泄漏处置、储存 国家危险化学品安全公共服务平台应急管理部化学品登记中心官方数据，站内按名称/CAS 检索可下载安全技术说明书（SDS） ChemicalBook理化性质、危规分类与原厂 SDS 跳转链接 合规化学网 · 免费 SDS《危险化学品目录》常见品种的合规 SDS（3000+ 份），站内检索后可免费下载

以上为第三方/官方站点，在本站新窗口打开；ICSC 未收录的化学品可能显示「未查到」，属正常结果。

以上内容来自 ERG 2024（美国政府作品）与机器翻译初稿，仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本；翻译未经专业复核的部分以英文原文为准。