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UN 2799 指南卡 137

苯基硫代磷酰二氯

Benzene phosphorus thiodichloride

危险性类别
8
包装类别
II
指南卡
137 · 物质——遇水反应——腐蚀性

TDG 运输品名（联合国《规章范本》）

正式运输品名危险性类别副危险包装类别
苯基硫代磷酰二氯8 —II

《危险化学品目录》关联

  • 苯硫代二氯化膦 CAS 3497-00-5 PubChem 桥接 皮肤腐蚀/刺激,类别1；严重眼损伤/眼刺激,类别1
全部可检索名称（2）
  • 苯基硫代磷酰二氯official · zh
  • Benzene phosphorus thiodichlorideen · en

潜在危害（火灾与爆炸）

除乙酸酐（UN1715，属易燃）外，其中某些物质可能燃烧，但均不易点燃。
EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily.
可能点燃可燃物（木材、纸张、油类、衣物等）。
May ignite combustibles (wood, paper, oil, clothing, etc.).
该物质会与水反应（某些剧烈），释放腐蚀性和（或）毒性气体及径流。
Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff.
易燃和（或）有毒气体可能积聚在受限区域（地下室、罐体、漏斗车或罐车等）。
Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.).
与金属接触可能释放易燃氢气。
Contact with metals may evolve flammable hydrogen gas.
容器受热或被水污染时可能爆炸。
Containers may explode when heated or if contaminated with water.
该物质可能以熔融状态运输。
Substance may be transported in a molten form.

健康危害

腐蚀性和（或）有毒；吸入、吞入或接触（皮肤、眼睛）蒸气、粉尘或该物质可能造成重伤、灼伤或死亡。
CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
火灾会产生刺激性、腐蚀性和（或）毒性气体。
Fire will produce irritating, corrosive and/or toxic gases.
与水反应可能产生大量热，使空气中烟气浓度升高。
Reaction with water may generate much heat that will increase the concentration of fumes in the air.
接触熔融物质可能造成皮肤和眼睛严重烧伤。
Contact with molten substance may cause severe burns to skin and eyes.
灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.

公众安全

拨打 119（火警）/120（急救）/110（报警）。然后拨打运输单据上的应急响应电话号码；如无运输单据或无人接听，请拨国家化学事故应急咨询专线 0532-83889090（24 小时），或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
无关人员远离。
Keep unauthorized personnel away.
位于上风向、地势较高处和（或）上游。
Stay upwind, uphill and/or upstream.
进入密闭空间前先通风，但仅在受过训练并配备装备时进行。
Ventilate closed spaces before entering, but only if properly trained and equipped.
立即预防措施
Immediate precautionary measure
向四周隔离泄漏区，液体至少 50 米（150 英尺），固体至少 25 米（75 英尺）。
Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
泄漏
Spill
高亮标注的物质：见表 1——初始隔离和防护距离。
For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
未高亮标注的物质：必要时在下风向加大立即预防措施的距离。
For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.
火灾
Fire
如罐车、铁路罐车或公路罐车涉及火灾，向四周隔离 800 米（1/2 英里）；同时考虑向四周 800 米（1/2 英里）实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

消防措施

物质未涉及火灾时，切勿将水施于物质本身。
When material is not involved in fire, do not use water on material itself.
小面积火灾
Small Fire
干粉或二氧化碳。
Dry chemical or CO2.
在安全可行的情况下，将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.
大面积火灾
Large Fire
用大量水淹没火场，同时用雾状水压降蒸气。如供水不足，救援人员应撤离。
Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply, responders should withdraw.
罐车火灾（罐车、铁路罐车或公路罐车）
Fire Involving Tanks, Rail Tank Cars or Highway Tanks
用大量水冷却容器，直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.
切勿让水进入容器内部。
Do not get water inside containers.
如泄压安全装置发出声响增大或罐体变色，立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.

防护服

佩戴正压自给式呼吸器（SCBA）。
Wear positive pressure self-contained breathing apparatus (SCBA).
在无火灾风险时，穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
消防员结构防护服可提供热防护，但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

泄漏处置

未穿着适当防护服时，切勿触碰破损容器或泄漏物。
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
在无风险的情况下堵漏。
Stop leak if you can do it without risk.
用喷雾水降低蒸气浓度；切勿将水直接施于泄漏处、泄漏区或容器内部。
Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container.
使可燃物（木材、纸张、油类等）远离泄漏物。
Keep combustibles (wood, paper, oil, etc.) away from spilled material.
少量泄漏
Small Spill
用干土、干沙或其他不燃材料覆盖，再盖上塑料布，以减少扩散或与雨水接触。
Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain.
使用清洁、无火花的工具收集物质，放入带松盖的塑料容器中待后续处置。
Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal.
防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.

急救

通用急救措施（各卡一致（18）
一般急救：
General First Aid:
拨打 120（急救）或呼叫急救医疗服务。
Call 911 or emergency medical service.
确保医务人员了解所涉及的物质，采取防护措施保护自身并避免沾染。
Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
在安全可行的情况下，将伤员移至新鲜空气处。
Move victim to fresh air if it can be done safely.
呼吸困难时给予吸氧。
Administer oxygen if breathing is difficult.
如伤员无呼吸：
If victim is not breathing:
切勿进行口对口人工呼吸；伤员可能已吞入或吸入该物质。
DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.
如具备条件且触及脉搏，清洗面部和口腔，然后使用合格的呼吸急救装置（球囊面罩、带单向阀的口袋面罩或其他装置）进行人工呼吸。
If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
如未触及脉搏或无呼吸急救装置，实施持续胸外按压。每两分钟检查一次脉搏，或观察有无自主呼吸的迹象。
If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
脱去并隔离受污染的衣物和鞋子。
Remove and isolate contaminated clothing and shoes.
少量皮肤接触时，避免将物质扩散到未受污染的皮肤上。
For minor skin contact, avoid spreading material on unaffected skin.
如接触该物质，立即用流动清水冲洗皮肤或眼睛至少 20 分钟。
In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
严重烧伤须立即就医。
For severe burns, immediate medical attention is required.
接触该物质（吸入、吞入或皮肤接触）后的症状可能出现延迟。
Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
保持伤员安静并保暖。
Keep victim calm and warm.
对伤员持续观察。
Keep victim under observation.
如需进一步救助，请联系当地中毒控制中心。
For further assistance, contact your local Poison Control Center.
注：基础生命支持（BLS）和高级生命支持（ALS）应由受过训练的专业人员实施。
Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.

本物质专项急救

特殊急救：
Specific First Aid:
腐蚀性物质接触人体时，立即用流动清水冲洗皮肤或眼睛至少 30 分钟。可能需要延长冲洗时间。
For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required.
从皮肤上清除凝固的熔融物须由医务人员协助。
Removal of solidified molten material from skin requires medical assistance.
在加拿大，本产品可能要求制定应急响应援助计划（ERAP）。请查阅运输单据和（或）「ERAP」章节。
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.
中国境内请拨：火警 119 · 急救 120 · 报警 110；化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090（24 小时）。英文原文沿用 ERG 原版（美国为 911）。

理化性质

PubChem 实验值

来自关联条目 苯硫代二氯化膦 CAS 3497-00-5 ——UN 条目常是类名，具体物质不同则数值可能不同，以 SDS 为准。

外观与性状
Phenylphosphorus thiodichloride is a colorless liquid with unpleasant acrid pungent odor. Corrodes metals slowly.

数据来自 PubChem（美国 NIH/NLM，CID 19016）实验值摘录，保留原值与单位未做换算。

权威数据源 · 更多资料

国际化学品安全卡（ICSC 中文版）ILO/WHO 编制的权威安全卡，收录约 1785 种常见危化品：危害、急救、泄漏处置、储存 国家危险化学品安全公共服务平台应急管理部化学品登记中心官方数据，站内按名称/CAS 检索可下载安全技术说明书（SDS） ChemicalBook理化性质、危规分类与原厂 SDS 跳转链接 合规化学网 · 免费 SDS《危险化学品目录》常见品种的合规 SDS（3000+ 份），站内检索后可免费下载

以上为第三方/官方站点，在本站新窗口打开；ICSC 未收录的化学品可能显示「未查到」，属正常结果。

以上内容来自 ERG 2024（美国政府作品）与机器翻译初稿，仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本；翻译未经专业复核的部分以英文原文为准。