UN 3119
指南卡 148
液态F型有机过氧化物,控制温度的
Organic peroxide type F, liquid, temperature controlled
- 危险性类别
- 5.2
- 包装类别
- —
- 指南卡
- 148 · 有机过氧化物(对热和杂质敏感/需控制温度)
TDG 运输品名(联合国《规章范本》)
| 正式运输品名 | 危险性类别 | 副危险 | 包装类别 |
|---|---|---|---|
| 液态F型有机过氧化物,控制温度的 | 5.2 | — | — |
全部可检索名称(2)
- 液态F型有机过氧化物,控制温度的
- Organic peroxide type F, liquid, temperature controlled
潜在危害(火灾与爆炸)
受热、混入杂质或温度失控可能爆炸。
May explode from heat, contamination or loss of temperature control.这些物质对温升特别敏感。超过规定的「控制温度」后,可能剧烈分解并起火。
These materials are particularly sensitive to temperature rises. Above a given "Control Temperature" they may decompose violently and catch fire.可能点燃可燃物(木材、纸张、油类、衣物等)。
May ignite combustibles (wood, paper, oil, clothing, etc.).暴露于空气可能自燃。
May ignite spontaneously if exposed to air.可能被热、火花或火焰点燃。
May be ignited by heat, sparks or flames.可能迅速燃烧并呈喷燃效应。
May burn rapidly with flare-burning effect.容器受热可能爆炸。
Containers may explode when heated.径流可能造成火灾或爆炸危险。
Runoff may create fire or explosion hazard.健康危害
火灾可能产生刺激性、腐蚀性和(或)毒性气体。
Fire may produce irritating, corrosive and/or toxic gases.吞入或接触(皮肤、眼睛)该物质可能造成重伤或灼伤。
Ingestion or contact (skin, eyes) with substance may cause severe injury or burns.灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.公众安全
拨打 119(火警)/120(急救)/110(报警)。然后拨打运输单据上的应急响应电话号码;如无运输单据或无人接听,请拨国家化学事故应急咨询专线 0532-83889090(24 小时),或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.无关人员远离。
Keep unauthorized personnel away.位于上风向、地势较高处和(或)上游。
Stay upwind, uphill and/or upstream.立即预防措施
Immediate precautionary measure向四周隔离泄漏区,液体至少 50 米(150 英尺),固体至少 25 米(75 英尺)。
Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.大量泄漏
Large Spill考虑向四周至少 250 米(800 英尺)实施初始疏散。
Consider initial evacuation for at least 250 meters (800 feet) in all directions.火灾
Fire如罐车、铁路罐车或公路罐车涉及火灾,向四周隔离 800 米(1/2 英里);同时考虑向四周 800 米(1/2 英里)实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.消防措施
该物质的温度必须始终保持在「控制温度」及以下。
The temperature of the substance must be maintained at or below the "Control Temperature" at all times.小面积火灾
Small Fire首选喷雾水或雾状水;如无水源,使用干粉、二氧化碳或普通泡沫。
Water spray or fog is preferred; if water not available use dry chemical, CO2 or regular foam.大面积火灾
Large Fire从远处向火场大量注水。
Flood fire area with water from a distance.使用喷雾水或雾状水;避免将直流水柱或实心水柱直接射向该产品。
Use water spray or fog; avoid aiming straight or solid streams directly onto the product.货物已受热时,切勿移动货物或车辆。
Do not move cargo or vehicle if cargo has been exposed to heat.在安全可行的情况下,将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.罐车火灾(罐车、铁路罐车或公路罐车)
Fire Involving Tanks, Rail Tank Cars or Highway Tanks从最远距离灭火,或使用无人操作的大口径水枪或遥控水炮。
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.用大量水冷却容器,直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.当心容器可能爆炸。
BEWARE OF POSSIBLE CONTAINER EXPLOSION.始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.大面积火灾时,使用无人操作的大口径水枪或遥控水炮;如无法做到,撤离现场并让其燃烧。
For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.防护服
佩戴正压自给式呼吸器(SCBA)。
Wear positive pressure self-contained breathing apparatus (SCBA).在无火灾风险时,穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.消防员结构防护服可提供热防护,但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.泄漏处置
切勿让该物质升温。使用干冰或冰等冷却剂(佩戴热防护手套)。如无法做到或无法取得冷却剂,立即撤离该区域。
DO NOT allow the substance to warm up. Use a coolant agent such as dry ice or ice (wear thermal protective gloves). If this is not possible or none can be obtained, evacuate the area immediately.消除周边区域的一切点火源(禁止吸烟、明火、火花或火焰)。
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.使可燃物(木材、纸张、油类等)远离泄漏物。
Keep combustibles (wood, paper, oil, etc.) away from spilled material.切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.在无风险的情况下堵漏。
Stop leak if you can do it without risk.少量泄漏
Small Spill用惰性、微湿的不燃材料,以清洁无火花的工具收集,放入带松盖的塑料容器中待后续处置。
Pick up with inert, damp, non-combustible material using clean, non-sparking tools and place into loosely covered plastic containers for later disposal.大量泄漏
Large Spill在液体泄漏物前方较远处筑堤围堵,待后续处置。
Dike far ahead of liquid spill for later disposal.防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.除专家监督外,切勿清理或处置。
DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.急救
本物质专项急救
特殊急救:
Specific First Aid:受污染的衣物干燥后可能有火灾风险。
Contaminated clothing may be a fire risk when dry.在加拿大,本产品可能要求制定应急响应援助计划(ERAP)。请查阅运输单据和(或)「ERAP」章节。
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.中国境内请拨:火警 119 · 急救 120 · 报警 110;化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090(24 小时)。英文原文沿用 ERG 原版(美国为 911)。
权威数据源 · 更多资料
国际化学品安全卡(ICSC 中文版)ILO/WHO 编制的权威安全卡,收录约 1785 种常见危化品:危害、急救、泄漏处置、储存
国家危险化学品安全公共服务平台应急管理部化学品登记中心官方数据,站内按名称/CAS 检索可下载安全技术说明书(SDS)
ChemicalBook理化性质、危规分类与原厂 SDS 跳转链接
合规化学网 · 免费 SDS《危险化学品目录》常见品种的合规 SDS(3000+ 份),站内检索后可免费下载
以上为第三方/官方站点,在本站新窗口打开;ICSC 未收录的化学品可能显示「未查到」,属正常结果。
以上内容来自 ERG 2024(美国政府作品)与机器翻译初稿,仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本;翻译未经专业复核的部分以英文原文为准。