指南卡 149
译本:机器初稿
物质(自反应)
Substances (Self-Reactive)
中国境内请拨:火警 119 · 急救 120 · 报警 110;化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090(24 小时)。英文原文沿用 ERG 原版(美国为 911)。
潜在危害(火灾与爆炸)
热、化学反应、摩擦或撞击可能引发自分解、自聚合或自燃。
Self-decomposition, self-polymerization, or self-ignition may be triggered by heat, chemical reaction, friction or impact.可能被热、火花或火焰点燃。
May be ignited by heat, sparks or flames.某些受热或涉及火灾时可能发生爆炸性分解。
Some may decompose explosively when heated or involved in a fire.标有 (P) 的物质在受热或涉及火灾时可能发生爆炸性聚合。
Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.可能剧烈燃烧。分解或聚合可能自行加速,并产生大量气体。
May burn violently. Decomposition or polymerization may be self-accelerating and produce large amounts of gases.蒸气或粉尘可能与空气形成爆炸性混合物。
Vapors or dust may form explosive mixtures with air.健康危害
吸入或接触蒸气、物质或分解产物可能造成重伤或死亡。
Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death.可能产生刺激性、毒性和(或)腐蚀性气体。
May produce irritating, toxic and/or corrosive gases.灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.公众安全
拨打 119(火警)/120(急救)/110(报警)。然后拨打运输单据上的应急响应电话号码;如无运输单据或无人接听,请拨国家化学事故应急咨询专线 0532-83889090(24 小时),或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.无关人员远离。
Keep unauthorized personnel away.位于上风向、地势较高处和(或)上游。
Stay upwind, uphill and/or upstream.立即预防措施
Immediate precautionary measure向四周隔离泄漏区,液体至少 50 米(150 英尺),固体至少 25 米(75 英尺)。
Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.大量泄漏
Large Spill考虑向四周至少 250 米(800 英尺)实施初始疏散。
Consider initial evacuation for at least 250 meters (800 feet) in all directions.火灾
Fire如罐车、铁路罐车或公路罐车涉及火灾,向四周隔离 800 米(1/2 英里);同时考虑向四周 800 米(1/2 英里)实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.消防措施
小面积火灾
Small Fire干粉、二氧化碳、喷雾水或普通泡沫。
Dry chemical, CO2, water spray or regular foam.大面积火灾
Large Fire从远处向火场大量注水。
Flood fire area with water from a distance.在安全可行的情况下,将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.罐车火灾(罐车、铁路罐车或公路罐车)
Fire Involving Tanks, Rail Tank Cars or Highway Tanks当心容器可能爆炸。
BEWARE OF POSSIBLE CONTAINER EXPLOSION.从最远距离灭火,或使用无人操作的大口径水枪或遥控水炮。
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.用大量水冷却容器,直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.如泄压安全装置发出声响增大或罐体变色,立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.防护服
佩戴正压自给式呼吸器(SCBA)。
Wear positive pressure self-contained breathing apparatus (SCBA).在无火灾风险时,穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.消防员结构防护服可提供热防护,但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.泄漏处置
消除周边区域的一切点火源(禁止吸烟、明火、火花或火焰)。
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.在无风险的情况下堵漏。
Stop leak if you can do it without risk.少量泄漏
Small Spill用惰性、微湿的不燃材料,以清洁无火花的工具收集,放入带松盖的塑料容器中待后续处置。
Pick up with inert, damp, non-combustible material using clean, non-sparking tools and place into loosely covered plastic containers for later disposal.防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.急救
适用物质(14 个物质)
- 5-叔丁基-2,4,6-三硝基间二甲苯(二甲苯麝香) UN 2956
- B型自反应液体 UN 3221
- B型自反应固体 UN 3222
- C型自反应液体 UN 3223
- C型自反应固体 UN 3224
- D型自反应液体 UN 3225
- D型自反应固体 UN 3226
- E型自反应液体 UN 3227
- E型自反应固体 UN 3228
- F型自反应液体 UN 3229
- F型自反应固体 UN 3230
- 偶氮甲酰胺 UN 3242
- 另作规定的液体聚合物质,稳定的,未另作规定的固体聚合物质,温度控制 UN 3531
- 聚合性物质,液态,稳定的,未另作规定的 UN 3532