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UN 3229 指南卡 149

F型自反应液体

Self-reactive liquid type F

危险性类别
4.1
包装类别
—
指南卡
149 · 物质（自反应）

TDG 运输品名（联合国《规章范本》）

正式运输品名危险性类别副危险包装类别
F型自反应液体4.1 ——
全部可检索名称（2）
  • F型自反应液体official · zh
  • Self-reactive liquid type Fen · en

潜在危害（火灾与爆炸）

热、化学反应、摩擦或撞击可能引发自分解、自聚合或自燃。
Self-decomposition, self-polymerization, or self-ignition may be triggered by heat, chemical reaction, friction or impact.
可能被热、火花或火焰点燃。
May be ignited by heat, sparks or flames.
某些受热或涉及火灾时可能发生爆炸性分解。
Some may decompose explosively when heated or involved in a fire.
标有 (P) 的物质在受热或涉及火灾时可能发生爆炸性聚合。
Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
可能剧烈燃烧。分解或聚合可能自行加速，并产生大量气体。
May burn violently. Decomposition or polymerization may be self-accelerating and produce large amounts of gases.
蒸气或粉尘可能与空气形成爆炸性混合物。
Vapors or dust may form explosive mixtures with air.

健康危害

吸入或接触蒸气、物质或分解产物可能造成重伤或死亡。
Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death.
可能产生刺激性、毒性和（或）腐蚀性气体。
May produce irritating, toxic and/or corrosive gases.
灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.

公众安全

拨打 119（火警）/120（急救）/110（报警）。然后拨打运输单据上的应急响应电话号码；如无运输单据或无人接听，请拨国家化学事故应急咨询专线 0532-83889090（24 小时），或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
无关人员远离。
Keep unauthorized personnel away.
位于上风向、地势较高处和（或）上游。
Stay upwind, uphill and/or upstream.
立即预防措施
Immediate precautionary measure
向四周隔离泄漏区，液体至少 50 米（150 英尺），固体至少 25 米（75 英尺）。
Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
大量泄漏
Large Spill
考虑向四周至少 250 米（800 英尺）实施初始疏散。
Consider initial evacuation for at least 250 meters (800 feet) in all directions.
火灾
Fire
如罐车、铁路罐车或公路罐车涉及火灾，向四周隔离 800 米（1/2 英里）；同时考虑向四周 800 米（1/2 英里）实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

消防措施

小面积火灾
Small Fire
干粉、二氧化碳、喷雾水或普通泡沫。
Dry chemical, CO2, water spray or regular foam.
大面积火灾
Large Fire
从远处向火场大量注水。
Flood fire area with water from a distance.
在安全可行的情况下，将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.
罐车火灾（罐车、铁路罐车或公路罐车）
Fire Involving Tanks, Rail Tank Cars or Highway Tanks
当心容器可能爆炸。
BEWARE OF POSSIBLE CONTAINER EXPLOSION.
从最远距离灭火，或使用无人操作的大口径水枪或遥控水炮。
Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
用大量水冷却容器，直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.
如泄压安全装置发出声响增大或罐体变色，立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.

防护服

佩戴正压自给式呼吸器（SCBA）。
Wear positive pressure self-contained breathing apparatus (SCBA).
在无火灾风险时，穿着制造商专门推荐的化学防护服。
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
消防员结构防护服可提供热防护，但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

泄漏处置

消除周边区域的一切点火源（禁止吸烟、明火、火花或火焰）。
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.
在无风险的情况下堵漏。
Stop leak if you can do it without risk.
少量泄漏
Small Spill
用惰性、微湿的不燃材料，以清洁无火花的工具收集，放入带松盖的塑料容器中待后续处置。
Pick up with inert, damp, non-combustible material using clean, non-sparking tools and place into loosely covered plastic containers for later disposal.
防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.

急救

通用急救措施（各卡一致（19）
一般急救：
General First Aid:
拨打 120（急救）或呼叫急救医疗服务。
Call 911 or emergency medical service.
确保医务人员了解所涉及的物质，采取防护措施保护自身并避免沾染。
Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
在安全可行的情况下，将伤员移至新鲜空气处。
Move victim to fresh air if it can be done safely.
呼吸困难时给予吸氧。
Administer oxygen if breathing is difficult.
如伤员无呼吸：
If victim is not breathing:
切勿进行口对口人工呼吸；伤员可能已吞入或吸入该物质。
DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.
如具备条件且触及脉搏，清洗面部和口腔，然后使用合格的呼吸急救装置（球囊面罩、带单向阀的口袋面罩或其他装置）进行人工呼吸。
If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
如未触及脉搏或无呼吸急救装置，实施持续胸外按压。每两分钟检查一次脉搏，或观察有无自主呼吸的迹象。
If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
脱去并隔离受污染的衣物和鞋子。
Remove and isolate contaminated clothing and shoes.
少量皮肤接触时，避免将物质扩散到未受污染的皮肤上。
For minor skin contact, avoid spreading material on unaffected skin.
如接触该物质，立即用流动清水冲洗皮肤或眼睛至少 20 分钟。
In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
严重烧伤须立即就医。
For severe burns, immediate medical attention is required.
接触该物质（吸入、吞入或皮肤接触）后的症状可能出现延迟。
Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
保持伤员安静并保暖。
Keep victim calm and warm.
对伤员持续观察。
Keep victim under observation.
如需进一步救助，请联系当地中毒控制中心。
For further assistance, contact your local Poison Control Center.
注：基础生命支持（BLS）和高级生命支持（ALS）应由受过训练的专业人员实施。
Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.
在加拿大，本产品可能要求制定应急响应援助计划（ERAP）。请查阅运输单据和（或）「ERAP」章节。
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.
中国境内请拨：火警 119 · 急救 120 · 报警 110；化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090（24 小时）。英文原文沿用 ERG 原版（美国为 911）。

权威数据源 · 更多资料

国际化学品安全卡（ICSC 中文版）ILO/WHO 编制的权威安全卡，收录约 1785 种常见危化品：危害、急救、泄漏处置、储存 国家危险化学品安全公共服务平台应急管理部化学品登记中心官方数据，站内按名称/CAS 检索可下载安全技术说明书（SDS） ChemicalBook理化性质、危规分类与原厂 SDS 跳转链接 合规化学网 · 免费 SDS《危险化学品目录》常见品种的合规 SDS（3000+ 份），站内检索后可免费下载

以上为第三方/官方站点，在本站新窗口打开；ICSC 未收录的化学品可能显示「未查到」，属正常结果。

以上内容来自 ERG 2024（美国政府作品）与机器翻译初稿，仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本；翻译未经专业复核的部分以英文原文为准。