UN 2213
指南卡 133
仲甲醛
Paraformaldehyde
- 危险性类别
- 4.1
- 包装类别
- III
- 指南卡
- 133 · 易燃固体
TDG 运输品名(联合国《规章范本》)
| 正式运输品名 | 危险性类别 | 副危险 | 包装类别 |
|---|---|---|---|
| 仲甲醛 | 4.1 | — | III |
全部可检索名称(2)
- 仲甲醛
- Paraformaldehyde
潜在危害(火灾与爆炸)
易燃或可燃物质。
Flammable/combustible material.可能被摩擦、热、火花或火焰点燃。
May be ignited by friction, heat, sparks or flames.某些可能迅速燃烧并呈喷燃效应。
Some may burn rapidly with flare-burning effect.粉末、粉尘、刨屑、钻屑、车屑或切屑可能爆炸或呈爆炸性剧烈燃烧。
Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence.该物质可能以熔融状态运输,温度可能高于其闪点。
Substance may be transported in a molten form at a temperature that may be above its flash point.火灾扑灭后可能复燃。
May re-ignite after fire is extinguished.健康危害
火灾可能产生刺激性和(或)毒性气体。
Fire may produce irritating and/or toxic gases.接触可能造成皮肤和眼睛灼伤。
Contact may cause burns to skin and eyes.接触熔融物质可能造成皮肤和眼睛严重烧伤。
Contact with molten substance may cause severe burns to skin and eyes.灭火用水或稀释水的径流可能造成环境污染。
Runoff from fire control or dilution water may cause environmental contamination.公众安全
拨打 119(火警)/120(急救)/110(报警)。然后拨打运输单据上的应急响应电话号码;如无运输单据或无人接听,请拨国家化学事故应急咨询专线 0532-83889090(24 小时),或查阅封底内页所列的相应电话号码。
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.无关人员远离。
Keep unauthorized personnel away.位于上风向、地势较高处和(或)上游。
Stay upwind, uphill and/or upstream.立即预防措施
Immediate precautionary measure向四周隔离泄漏区至少 25 米(75 英尺)。
Isolate spill or leak area for at least 25 meters (75 feet) in all directions.大量泄漏
Large Spill考虑在下风向至少 100 米(330 英尺)范围内实施初始疏散。
Consider initial downwind evacuation for at least 100 meters (330 feet).火灾
Fire如罐车、铁路罐车或公路罐车涉及火灾,向四周隔离 800 米(1/2 英里);同时考虑向四周 800 米(1/2 英里)实施初始疏散。
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.消防措施
小面积火灾
Small Fire干粉、二氧化碳、沙子、土、喷雾水或普通泡沫。
Dry chemical, CO2, sand, earth, water spray or regular foam.大面积火灾
Large Fire喷雾水、雾状水或普通泡沫。
Water spray, fog or regular foam.在安全可行的情况下,将未受损的容器移离火场周边区域。
If it can be done safely, move undamaged containers away from the area around the fire.金属颜料或膏状物火灾(例如「铝粉漆」)
Fire Involving Metal Pigments or Pastes (e.g. "Aluminum Paste")铝粉漆火灾应按可燃金属火灾处置。使用干沙、石墨粉、干氯化钠基灭火器或 D 类灭火器。另见指南 170。
Aluminum Paste fires should be treated as a combustible metal fire. Use DRY sand, graphite powder, dry sodium chloride-based extinguishers or class D extinguishers. Also, see GUIDE 170.罐车火灾(罐车、铁路罐车或公路罐车)
Fire Involving Tanks, Rail Tank Cars or Highway Tanks用大量水冷却容器,直至火灾扑灭后很长时间。
Cool containers with flooding quantities of water until well after fire is out.大面积火灾时,使用无人操作的大口径水枪或遥控水炮;如无法做到,撤离现场并让其燃烧。
For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.如泄压安全装置发出声响增大或罐体变色,立即撤离。
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.始终远离直接接触火焰的罐体。
ALWAYS stay away from tanks in direct contact with flames.防护服
佩戴正压自给式呼吸器(SCBA)。
Wear positive pressure self-contained breathing apparatus (SCBA).消防员结构防护服可提供热防护,但化学防护能力有限。
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.泄漏处置
消除周边区域的一切点火源(禁止吸烟、明火、火花或火焰)。
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.切勿触碰或踩踏泄漏物。
Do not touch or walk through spilled material.少量干泄漏
Small Dry Spill用清洁的铲子将物质装入清洁干燥的容器,松松盖上;将容器移出泄漏区。
With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.大量泄漏
Large Spill用水润湿并筑堤围堵,待后续处置。
Wet down with water and dike for later disposal.防止泄漏物进入水体、下水道、地下室或受限空间。
Prevent entry into waterways, sewers, basements or confined areas.急救
本物质专项急救
特殊急救:
Specific First Aid:从皮肤上清除凝固的熔融物须由医务人员协助。
Removal of solidified molten material from skin requires medical assistance.在加拿大,本产品可能要求制定应急响应援助计划(ERAP)。请查阅运输单据和(或)「ERAP」章节。
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.中国境内请拨:火警 119 · 急救 120 · 报警 110;化学品泄漏或中毒另可拨国家化学事故应急咨询专线 0532-83889090(24 小时)。英文原文沿用 ERG 原版(美国为 911)。
权威数据源 · 更多资料
国际化学品安全卡(ICSC 中文版)ILO/WHO 编制的权威安全卡,收录约 1785 种常见危化品:危害、急救、泄漏处置、储存
国家危险化学品安全公共服务平台应急管理部化学品登记中心官方数据,站内按名称/CAS 检索可下载安全技术说明书(SDS)
ChemicalBook理化性质、危规分类与原厂 SDS 跳转链接
合规化学网 · 免费 SDS《危险化学品目录》常见品种的合规 SDS(3000+ 份),站内检索后可免费下载
以上为第三方/官方站点,在本站新窗口打开;ICSC 未收录的化学品可能显示「未查到」,属正常结果。
以上内容来自 ERG 2024(美国政府作品)与机器翻译初稿,仅供应急处置参考。现场决策应结合专业训练、当地预案与官方文本;翻译未经专业复核的部分以英文原文为准。